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Quo Vadis Chemie - Dr. Radim Hrdina: C-H Functionalization Adamantane Derivatives

Two main approaches to 1,2-disubstituted adamantane derivatives from readily available starting materials (alcohols, carboxylic acids, amines) will be presented: A rhodium acetate catalyzed intramolecular nitrene insertion reaction of sulfonamides and carbamates; and palladium acetate catalyzed arylation/ acetoxylation of C−H bonds. Mechanistic studies of these transformations, postfunctionalizations and application of obtained derivatives will be discussed in detail. The lecture takes place at Ch-2 Lecture Hall on Monday 3rd, 3 pm.



Published: Mar 22, 2017 11:05 AM

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