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Quo Vadis Chemie: Zeolite-templated 3-D graphene-like microporous carbons

The lecture will be held by prof. Ryong Ryoo of KAIST University in Daejeon, South Korea. He is the head of the Center for Functional Nanomaterials. Ryoo has won a variety of awards, including the Top Scientist Award given by the South Korean government in 2005. He obtained the KOSEF Science and Technology Award in 2001 for his work on the synthesis and crystal structure of mesoporous silica. The lecture will take place at Ch2 Lecture Hall on Monday 23th of May, 2 pm.
When May 23, 2016
from 02:00 PM to 03:30 PM
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Thermal carbonization of organic substances within porous inorganic template has been well known for many years as a synthetic route to nanoporous carbons. When the templating approach is applied to mesoporous templates, the template pores can be perfectly replicated into carbon frameworks. After removal of the templates, the template-free carbons exhibit highly ordered mesoporous structures inherited from the templates. However, when the templated synthesis is applied to smaller-pore, microporous zeolite templates, the carbonization results in carbon deposition outside the template pores as well as at the internal pores.

The non-selective carbon deposition is so far the chief obstacle to research activities on the zeolite-templated microporous carbons. Here, we demonstrate that graphene-like carbon frameworks can be selectively formed inside the zeolite micropores without carbon deposition at the external surfaces by incorporating carbonization transition metal catalysts into the zeolite pores. X-ray crystallographic analysis using zeolite single crystals shows that a curved graphene-like layer of carbon atoms is generated along the zeolite pore walls. Resultantly, the carbon products liberated from the zeolite templates are composed of uniform and ordered micropores with fully graphene-like frameworks. Furthermore, the synthesis can be scaled up readily, which is important for various practical applications such as absorbents, Li-ion batteries, and zeolite-like carbon catalysts.

Published: May 17, 2016 11:05 AM

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